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Synergic effect of palladium-based bimetallic catalysts for the hydrogenation of nitroaromatics
Authors:Bo-Shun Wan   Shi-Jian Liao   Yun Xu  Dao-Rong Yu
Affiliation:(1) Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O. Box 110, 116023 Dalian, P. R. China
Abstract:Bimetallic catalysts, PdCl2-MXn and PdCl2(PhCN)2-Mxn (MXn=FeCl3, Fe(acac)3, Co(OAc)2, CoCl2, Co(acac)2, NiCl2, Ni(OAc)2, RuCl3, Cu(OAc)2, CuCl2), exhibit remarkable synergic effect which can obviously increase the activity of the monometallic Pd catalyst for the hydrogenation of nitroaromatics, whereas MXn alone is not catalytically active under the same reaction conditions.
Keywords:Synergic effect  bimetallic catalysts  hydrogenation
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