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Highly enantioselective catalytic [6+3] cycloadditions of azomethine ylides |
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| Authors: | Marco Potowski Jonathan O Bauer Carsten Strohmann Andrey P Antonchick Herbert Waldmann |
| Institution: | 1. Max‐Planck‐Institut für Molekulare Physiologie, Abteilung Chemische Biologie, Otto‐Hahn‐Strasse 11, 44227 Dortmund (Germany);2. Technische Universit?t Dortmund, Fakult?t Chemie, Chemische Biologie, Otto‐Hahn‐Strasse 6, 44221 Dortmund (Germany);3. Technische Universit?t Dortmund, Fakult?t Chemie, Anorganische Chemie, Otto‐Hahn‐Strasse 6, 44221 Dortmund (Germany) |
| Abstract: | Under control: Highly functionalized chiral annulated piperidines with eight stereocenters are efficiently obtained by means of a highly enantioselective one-pot 6+3]/4+2] sequence. This sequence included the first enantioselective 6+3] cycloaddition of azomethine ylides with fulvenes. |
| Keywords: | asymmetric catalysis cycloaddition azomethine ylides fulvene piperidine |
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