17O NMR investigation of phosphite hydrolysis mechanisms |
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| Authors: | McIntyre Sarah K Alam Todd M |
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| Institution: | Department of Electronic and Nanostructured Materials, Sandia National Laboratories, Albuquerque, NM 87185-0886, USA. |
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| Abstract: | The use of solution 17O NMR spectroscopy in verifying the mechanism of trialkyl phosphite hydrolysis is presented. Trimethyl phosphite was reacted with 17O-labeled H2O at different temperatures and two reactant concentrations, with the reaction being monitored by 17O NMR. Kinetic details elucidated from the NMR spectra are also discussed. |
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| Keywords: | NMR 17O NMR alkyl phosphites phosphite esters phosphite hydrolysis |
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