The synthesis of tris(perfluoroalkyl)phosphines |
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| Authors: | Murphy-Jolly Makeba B Lewis Lesley C Caffyn Andrew J M |
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| Affiliation: | Department of Chemistry, The University of the West Indies, St. Augustine, Trinidad & Tobago. acaffyn@fsa.uwi.tt. |
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| Abstract: | Tris(perfluoroalkyl)phosphines, of interest as tunable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines. |
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