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Magnetic coupling in Gd(Fe6−x Cr x )Al6: A57Fe Mössbauer study
Authors:Hong-Shuo Li  J M Cadogan  Xiao-Li Zhao  S J Campbell
Institution:(1) School of Physics, The University of New South Wales, 2052 Sydney, NSW, Australia;(2) Department of Physics, University College, The University of New South Wales, 2600 Canberra, ACT, Australia
Abstract:57Fe Mössbauer measurements have been made on the ternary ThMn12-type intermetallic compounds Gd(Fe6–x Cr x )Al6 withx=0, 0.5, 1.0, 1.5 and 2.0, at temperatures of 4.2 and 77 K. The principal effect of the Cr substitution is to reduce the57Fe magnetic hyperfine field at 4.2 K in this series. The analysis of the57Fe Mössbauer spectra is consistent with a ferromagnetic coupling between the Gd and Cr magnetic moments. These results are in agreement with previous studies by Felner et al. on GdCr6Al6, in which a ferromagnetic ordering withT C=170 K was observed.On leave from Applied Acoustics Institute, Shaanxi Teachers University, Xian, PR China.
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