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Simple preparation of diamondoid 1,3-dienes via oxetane ring opening |
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| Authors: | Fokin Andrey A Butova Ekaterina D Chernish Lesya V Fokina Natalie A Dahl Jeremy E P Carlson Robert M K Schreiner Peter R |
| Institution: | Department of Organic Chemistry, Kiev Polytechnic Institute, pr. Pobedy 37, 03056 Kiev, Ukraine. aaf@xtf.ntu-kpi.kiev.ua |
| Abstract: | The transformations of apical mono- and bisacetyl diamondoids to the respective oxetanes and subsequent acid-catalyzed ring opening/dehydration lead to diamondoidyl mono- and bis-1,3-dienes in high preparative yields. |
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