Band intensities in the circular dichroism and absorption spectra and the states of <Emphasis Type="Italic">d</Emphasis> ions in absorbing media: I. Octahedrally coordinated positions of <Emphasis Type="Italic">d</Emphasis> ions |
| |
Authors: | Email author" target="_blank">T?F?Vereme?chikEmail author |
| |
Institution: | 1.Shubnikov Institute of Crystallography,Russian Academy of Sciences,Moscow,Russia |
| |
Abstract: | The factors affecting the band intensity in circular dichroism (CD) and absorption spectra (selection rules, point group of
structural position, and the electron density of the ground state of octahedrally coordinated d ion in absorbing medium) are considered. The intensities of CD and absorption bands are calculated and compared with the
experimental data. It is shown that the differences in the spatial inversion of the electric- and magnetic-dipole moment transformations
lead to a more rigorous validity of the symmetry selection rules and increase the resolution of peaks and transparency window
of medium absorption in CD spectra (in contrast to absorption ones). Some criteria for estimating the valence and structural
states of d ions are formulated. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |