Metal nitrite: a powerful oxidizing reagent |
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| Authors: | Baidya Mahiuddin Yamamoto Hisashi |
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| Institution: | Department of Chemistry, The University of Chicago, Illinois 60637, United States. |
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| Abstract: | An efficient and simple source of nitroso reagents and their oxidation reactions are described. The combination of a Lewis acid and a metal nitrite was applied to the oxidation of silyl enol ethers. Amino acid and peptide derivatives were easily accessed through in situ C-C bond cleavage of fully substituted silyl enol ethers upon oxidation. |
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