| 纤维素基磁性聚氨肟树脂的研究 |
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| 引用本文： | 林力克,杨超雄,吴锦远,杜光军.纤维素基磁性聚氨肟树脂的研究[J].广州化学,1993(4). |
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| 作者姓名： | 林力克 杨超雄 吴锦远 杜光军 |
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| 作者单位： | 中国科学院广州化学研究所，中国科学院广州化学研究所，中国科学院广州化学研究所，中国科学院广州化学研究所 |
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| 基金项目： | 国家自然科学基金，中国科学院广州化学研宄所纤维素化学开放研宄实验室资助项目 |
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| 摘 要： | 用醋酸纤维素包埋γ-Fe_2O_3作磁芯,经过接枝改性,首次合成了纤维素基聚氨肟树脂(MPAO)。实验结果表明,树脂有效地吸附Hg~(2-)、Cu~(2-)、Pb~(2+)、Ni~(2-)等重金属离子,优点是吸附速度快、易洗脱。吸附动力学证明化学反应是吸附速度的决定因素,与树脂吸附层的非交联结构有关。
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| 关 键 词： | 纤维素 磁性聚氨肟树脂 醋酸纤维素 |
STUDY ON THE CELLULOSE--BASED MAGNETIC POLYAMIDOXIME ADSORBENTS RESINS |
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| Lin Like,Yang Chaoxiong,Wu Jinyuan Du Guangjun Guangzhou Institute of Chemistry,Academia Sinica,Guangzhou,China.STUDY ON THE CELLULOSE--BASED MAGNETIC POLYAMIDOXIME ADSORBENTS RESINS[J].Guangzhou Chemistry,1993(4). |
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| Authors: | Lin Like Yang Chaoxiong Wu Jinyuan Du Guangjun Guangzhou Institute of Chemistry Academia Sinica Guangzhou China |
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| Abstract: | The cellulose-based magnetic polyamidoxime adsorbent (MPAO) were successful prepared first in our laboratory by the radical—induced graft polymerization of acrylonitrile onto γ-ferric oxide—embeding cellulose particles following by amidoximation with hydroxylamine. The experimental results indicate that these adsorbents are suitable for uptake of the heavy metal ions such as Hg~(2+), Cu~(2+), Pb~(2+) and Ni~(2+), etc. It combines the advantages of high adsorption rate with easy elution for bivalent cations listed above. From the data of adsorption kinetics studies, the adsorption rate was found to be controlled by the coordination reaction rather than mass transfer effects. |
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| Keywords: | Cellulose Cellulose acetate magnetic resin Polyamidoxime adsorbent |
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