Stereochemistry of ethynylation reaction of C2 isomeric 1,2-dimethyldecahydroquinol-4-ones |
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Authors: | A. A. Akhrem L. I. Ukhova N. F. Uskova |
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Affiliation: | (1) Institute of Physicoorganic Chemistry, Academy of Sciences of the USSR, USSR;(2) N. D. Zelinskii Institute of Organic Chemistry Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions The stereochemistry of the ethynylation reaction of the C2 epimers of 1,2-dimethyldecahydroquinol-4-ol with sodium acetylide in liquid ammonia has been studied and the conformation of the acetylene alcohols formed by this has been established.Translated from Izvestiya Akademii Nauk SSSR, SeriyaKhimicheskaya, No. 4, pp. 900–903, April, 1970. |
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