Synthesis of an aluminum spirocyclic hybrid with an inorganic B2O3 and an organic C3N2 core |
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Authors: | Yang Zhi Ma Xiaoli Oswald Rainer B Roesky Herbert W Noltemeyer Mathias |
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Institution: | Institut für Anorganische Chemie der Universit?t G?ttingen, Tammannstrasse 4, D-37077 G?ttingen, Germany. |
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Abstract: | The reaction of LAl (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) or LAlH2 with PhB(OH)2 yields the unprecedented spirocyclic LAl(OBPh)2O] compound. The former reaction proceeds under hydrogen formation and simultaneous oxidation of the aluminum(I). |
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