Synthesis of multisubstituted furans, pyrroles, and thiophenes via ynolates |
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| Authors: | Shindo Mitsuru Yoshimura Yutaka Hayashi Maiko Soejima Hiroe Yoshikawa Takashi Matsumoto Kenji Shishido Kozo |
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| Affiliation: | Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Japan. shindo@cm.kyushu-u.ac.jp |
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| Abstract: | An efficient synthetic method for the preparation of multisubstituted furans, thiophenes, and pyrroles using ynolates was developed. This novel formal [4 + 1] annulation by C2-C3 and C3-C4 bond formations includes cycloaddition, cyclization, decarboxylation, and dehydration as key steps. |
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