| 硫酸羟胺与水合肼对B-Z反应的影响 |
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| 引用本文： | 黄振炎,周开雄.硫酸羟胺与水合肼对B-Z反应的影响[J].物理化学学报,1994,10(5):449-451. |
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| 作者姓名： | 黄振炎 周开雄 |
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| 作者单位： | Department of Chemistry, Wenzhou Teachers' College, Zhejiang Wenzhou 325000 |
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| 摘 要： | 化学振荡与生化、生理现象关系密切，有维生素C参与的化学振荡反应也很引人注目．赵学庄等对维生素C存在的B－Z反应的振荡行为与机理进行了研究．他们的实验表明，当加入维生素C时，B-Z反应的诱导期增长，振荡周期增大，振荡寿命缩短，与向反应体系加入等量的Br-所产生的影响是一致的，并由此推断，维生素C对B－Z反应的影响可能是由维生素C与BrO反应生成Br-抑制了此反应的化学振荡，据此，凡是能与BrO反应生成Br-的物质，其对B－Z反应的影响必将类似于维生素C，硫酸羟胺与水合肼就属于此类物质．本文初步研究了它们对B－Z反应的影…
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| 关 键 词： | 硫酸羟胺 水合肼 B-Z反应 |
| 收稿时间： | 1992-10-15 |
| 修稿时间： | 1993-01-18 |
The Effects of Hydroxylamine Sulfate and Hydrated Hydrazine on the B-Z Reaction |
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| Huang Zhenyan, Zhou Kaixiong.The Effects of Hydroxylamine Sulfate and Hydrated Hydrazine on the B-Z Reaction[J].Acta Physico-Chimica Sinica,1994,10(5):449-451. |
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| Authors: | Huang Zhenyan Zhou Kaixiong |
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| Institution: | Department of Chemistry, Wenzhou Teachers' College, Zhejiang Wenzhou 325000 |
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| Abstract: | In this paper the effects of hydroxylamine sulfate and hydrated hydrazine on the B-Z reaction are studied. Hydroxylamine sulfate and hydrated hydrazine can react with BrO to produce Br-. They show some analogies with vitamin C in their effects on B-Z reaction, that is, they sbolarly lengthen the induction period and oscillating period,and shorten the life-span of this oscillating reaction.From this reason the conjecture of reaction mechanism that is proposed by Zhao Xuezhuang et al can be confirmed. |
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| Keywords: | Hydroxylamine sulfate Hydrated hydrazine B-Z reaction |
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