| 紫外激光诱导C60与M(CO)6(M=Cr,Mo, W)的配位反应 |
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| 引用本文： | 张杰,林金谷,王文华,佘永柏,傅克坚. 紫外激光诱导C60与M(CO)6(M=Cr,Mo, W)的配位反应[J]. 物理化学学报, 1994, 10(2): 145-150. DOI: 10.3866/PKU.WHXB19940211 |
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| 作者姓名： | 张杰 林金谷 王文华 佘永柏 傅克坚 |
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| 作者单位： | Institute of Physics, Chinese Academy of Sciences, Beijing 100080 |
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| 摘 要： | 研究了用紫外激光(355 nm)诱导C_(60)与金属羰基化合物M(CO)_6(M＝Cr；Mo，W)的配位反应，合成了具有C_(4υ)对称性的配位络合物(η~2－C_(60))M(CO)_5，并初步讨论了C_(60)与M(CO)_6反应的动力学过程．
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| 关 键 词： | C60 M(CO)6(M=Cr Mo和W) 紫外激光 配位反应 |
| 收稿时间： | 1992-10-05 |
| 修稿时间： | 1993-03-06 |
UV Laser Induced Coordinative Reaction btween C_60 and M(CO)_6 (M=Cr, Mo and W) |
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| Zhang Jie, Lin Jinggu, Wang Wenhua, She Yongbo, Fu Kejian. UV Laser Induced Coordinative Reaction btween C_60 and M(CO)_6 (M=Cr, Mo and W)[J]. Acta Physico-Chimica Sinica, 1994, 10(2): 145-150. DOI: 10.3866/PKU.WHXB19940211 |
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| Authors: | Zhang Jie Lin Jinggu Wang Wenhua She Yongbo Fu Kejian |
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| Affiliation: | Institute of Physics, Chinese Academy of Sciences, Beijing 100080 |
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| Abstract: | In this paper, laser induced coordinative reactions between C_(60) and M(CO)_6 (M=Cr, Mo and W) are carried out and complexes (η~2-C_(60)) M(CO)_5 are formed. The dymamics of reaction are also tentatively discussed. |
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| Keywords: | C_60 M(CO)_6(M=Cr Mo and W) UV laser Coordinative reactions |
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