| CO(α3П)与CN(X 2Σ +)的能量转移反应 |
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| 引用本文： | 倪晋智,李书涛,储焰南,胡义华,曹德兆.CO(α3П)与CN(X 2Σ +)的能量转移反应[J].物理化学学报,1994,10(1):19-21. |
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| 作者姓名： | 倪晋智 李书涛 储焰南 胡义华 曹德兆 |
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| 作者单位： | Laser Spectroscopy Laboratory, Anhui Institute of Pptics and Fine Mechanics, Academia Sinica, Hefei 230031 |
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| 摘 要： |
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| 关 键 词： | 亚稳态CO(a)分子 CN自由基 能量转移 |
| 收稿时间： | 1993-09-14 |
| 修稿时间： | 1994-01-15 |
Energy Transfer Reaction of Metastable CO(α3П) Molecule with CN Radical |
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| Ni Jin-Zhi,Li Shu-Tao,Chu Yan-Nan,Hu Yi-Hua,Cao De-Zhao.Energy Transfer Reaction of Metastable CO(α3П) Molecule with CN Radical[J].Acta Physico-Chimica Sinica,1994,10(1):19-21. |
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| Authors: | Ni Jin-Zhi Li Shu-Tao Chu Yan-Nan Hu Yi-Hua Cao De-Zhao |
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| Institution: | Laser Spectroscopy Laboratory, Anhui Institute of Pptics and Fine Mechanics, Academia Sinica, Hefei 230031 |
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| Abstract: | Energy-transfer reaction from metastable CO(a~3П) molecule to CN radical has been studied in a room-temperature flow reactor. The CN (B-X, △v=0, ±1, ±2) violet emission bands were obtained. The △v=0 sequence of CN(B) were analyzed by computer simulation. The vibrational temperature is 3400 K. By using the reference reaction CO(a)+NO, the formation rate constant of CN(B) has been measured, k_(CN)(B)=1.1×10~(-11) cm~3·molecule~(-1)·s~(-1). |
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| Keywords: | Metastable CO(a) molecule CN radical Energy transfer |
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