| 利用大分子单体技术合成接枝共聚物 |
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| 引用本文： | 邱永兴,封麟先.利用大分子单体技术合成接枝共聚物[J].功能高分子学报,1991,4(2):81-95. |
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| 作者姓名： | 邱永兴 封麟先 |
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| 作者单位： | 浙江大学化学系，浙江大学化学系，浙江大学化学系，浙江大学化学系 杭州 310027，杭州 310027，杭州 310027，杭州 310027 |
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| 摘 要： | 大分子单体和小分子共单体共聚是合成接枝共聚物的重要途径之一。本文综述了大分子单体通过各种聚合方式(自由基共聚、离子型共聚、配位共聚、基团转移共聚和逐步共聚)和普通小分子单体的共聚反应,详细讨论了大分子单体和小分子单体的自由基共聚反应动力学,并简要介绍了接枝共聚物的应用背景。
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| 关 键 词： | 大分子单体 接枝共聚物 竞聚率 |
The Synthesis of Graft Copolymers by Way of Macromer Technique |
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| Qiu Yongxing Feng Linxian Yu Xiaojie Yang Shilin.The Synthesis of Graft Copolymers by Way of Macromer Technique[J].Journal of Functional Polymers,1991,4(2):81-95. |
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| Authors: | Qiu Yongxing Feng Linxian Yu Xiaojie Yang Shilin |
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| Abstract: | The copolymerization of macromers with comonomers proves to be one of the most important ways of synthesizing well-defined graft copolymers. Various kinds of functional graft copolymers can be prepared by radical copolymerization, ionic copolymerization, coordination copolymerization, group transfer copolymerization and step growth copolymerization of macroiners with comonomers. The radical copolymerization kinetics of macromers has been reviewed in detail and the applications of graft copolymers have been introduced briefly. |
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| Keywords: | macromer copolymerization reactivity ratio copolymerization kinetics graft copolymer |
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