Zwei neue Erdalkalimetall-Oxoindate: BaCa2In6O12 und BaSr2In6O12 |
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Authors: | A. Lalla,H. K. Mü ller-Buschbaum |
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Abstract: | Two New Alkaline-Earth-Oxoindates: BaCa2In6O12 and BaSr2In6O12 The hitherto unknown compounds (I): BaCa2In6O12 and (II): BaSr2In6O12 were prepared and examined by single crystal X-Ray work. (I) and (II) crystallize with hexagonal symmetry, space group C? P63/m, with (I): a = 9.880, c = 3.211 Å; (II): a = 9.9443; c = 3.2671 Å, Z = 1. Both compounds are isotypic to the metastable oxide AM2Ln6O12, but without metastable behavior. The [In6O12]6? network is occupied by the alkaline earth ions. One of the tunnels is stuffed by Ca2+ and Sr2+ respectively, the other one by Ba2+ in a statistical distribution on possible point positions. (I) and (II) prove the existence of the AM2Ln6O12-type in respect to small Ln3+ ions. |
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