Zur Struktur und Reaktivität von stannylierten Propylaminen und -sulfiden. Kristall- und Molekülstruktur von Bis(3-dimethylchlorostannylpropyl)sulfid S(CH2CH2CH2SnMe2Cl)2

Structure and Reactivity of Stannylated Propyl Amines and Propyl Sulfides. Crystal and Molecular Structure of Bis(3-chlorodimethylstannylpropyl)sulfide S(CH₂CH₂CH₂SnMe₂Cl)₂ The synthesis and reactivity of stannylated propyl amines and propyl sulfides, respectively, E(CH₂CH₂CH₂SnMe₃)₂ ( 1 , E ? NMe; 2 E ? S) and N(CH₂CH₂CH₂SnMe₃)₃ 3 are reported. 1 and 3 react with dimethyl dichlorostannane under thermal cyclisation to 1,5-dimethyl-5-chloro-1aza-5-stannabicyclo3.3.0^1,5]octane Me(Cl)Sn(CH₂CH₂CH₂)₂NMe 4 and 5-chloro-1-aza-5-stannatricyclo3.3.3.0^1,5]-undecane ClSn(CH₂CH₂CH₂)₃N 5 , respectively. The reaction of 2 with dimethyl dichlorostannane leads to the formation of bis(3-chloro-dimethylstannylpropyl)sulfide S(CH₂CH₂CH₂SnMe₂Cl)₂ 6 , whereas the treatment of 2 with tin tetrachloride yields the bis(3-di-chloro-methylstannylpropyl)sulfide S(CH₂CH₂CH₂SnMeCl₂)₂ 7 . The ¹H, ¹³C, and ¹¹⁹Sn NMR data are discussed. 6 crystallizes in the ortho-rhombic space group Pna2₁ with the unit cell parameters a = 2275.0(1), b = 733.6(2), c = 1062.0(4) pm, V = 1.77273 nm³, Z = 4. The structure was refined to a final R value of 0.041. Both tin atoms adopt distorted trigonal bipyramidal configurations as a result of intramolecular interactions with the bridging sulphur. The sulphur and the chlorine atoms occupy the apical positions. The Sn? S distances amount to 309.7(4) and 311.8(4) pm.