Abstract: | Dust-free semidilute and concentrated polystyrene(PS)solutions in different solvents were prepared by slow evaporation and in situ anionic polymerization,which removes the effects of troublesome artifacts such as dust contamination and concentration gradient.The dynamics was reexamined by a combination of static and dynamic laser light scattering.In benzene and toluene(good solvents for PS),only one fast diffusive mode of polymer chains can be observed when the concentration(c)is up to 20%,which is attri... |