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A SLOW RELAXATION MODE OF POLYMER CHAINS IN A SEMIDILUTE SOLUTION
Authors:Jun-fang Li  Yi-jie Lu  Guang-zhao Zhang  

Wei Li
  Chi Wu

Abstract:Dust-free semidilute and concentrated polystyrene(PS)solutions in different solvents were prepared by slow evaporation and in situ anionic polymerization,which removes the effects of troublesome artifacts such as dust contamination and concentration gradient.The dynamics was reexamined by a combination of static and dynamic laser light scattering.In benzene and toluene(good solvents for PS),only one fast diffusive mode of polymer chains can be observed when the concentration(c)is up to 20%,which is attri...
Keywords:Semidilute  Anionic polymerization  Laser light scattering  Blob  Correlation length  Slow mode
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