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Reaction of benzyl chloride with propylene and trifluoropropene under metallocomplex initiation conditions
Authors:T. T. Vasil'eva  I. A. Fokina  S. V. Vitt
Affiliation:(1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
Abstract:The reactions of benzyl chloride with propylene and 3,3,3-trifluoropropene in the presence of Fe(CO)5 ` + DMF were studied. With propylene, the reaction stops at the addition stage with the simultaneous formation of dibenzyl. In the case of 3,3,3-trifluoropropene, a telomerization takes place, whereby the second growing radical C6H5CH2CH2CH(CF3)CH2CdotHCF3 practically completely isomerizes with a 1,5-migration into the radical C6H5CdotHCH2CH(CF3)CH2CH2CF3. To confirm the structure of the isolated compounds, chromato-mass-spectrometry and13C NMR were used.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1384–1388, June, 1991.
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