Enantioselective total synthesis of both diastereomers of preclavulone-A methyl ester |
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Authors: | Hisanaka Ito |
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Affiliation: | School of Life Science, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan |
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Abstract: | The enantioselective total synthesis of preclavulone-A methyl ester and its diastereomer was achieved from enantiomerically pure 5 in a stereocontrolled manner. The absolute stereochemistry of naturally occurring preclavulone-A methyl esters was determined by comparison of the [α]D value. |
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