Palladium-catalyzed syntheses of tetrahydrocarbazolones as advanced intermediates to carbazole alkaloids |
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Authors: | Tricia L Scott |
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Institution: | C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, WV 26506-6045, USA |
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Abstract: | Two sequential palladium-catalyzed reactions, an intermolecular Stille cross-coupling followed by a recently developed palladium-catalyzed reductive N-heteroannulation, have been employed as the key synthetic steps toward six tetrahydrocarbazolones. The products are advanced intermediates toward a number of naturally occurring carbazole alkaloids. |
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Keywords: | Carbazoles Palladium-catalyzed Alkaloids |
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