A novel method for the reduction of sulfoxides and pyridine N-oxides with the system silane/MoO2Cl2 |
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| Authors: | Ana C Fernandes Carlos C Romão |
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| Institution: | Instituto de Tecnologia Química e Biológica da Universidade Nova de Lisboa, Quinta do Marquês, EAN, Apt 127, 2781-901 Oeiras, Portugal |
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| Abstract: | A novel method for the reduction of sulfoxides and pyridine N-oxides using a silane and a catalytic amount of MoO2Cl2 in excellent yields and with a wide functional group tolerance is reported. A green protocol for this reaction was developed in water with the air-stable catalytic system PMHS/MoO2Cl2(H2O)2. |
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| Keywords: | Reduction Sulfoxides Pyridine N-oxides Dioxomolybdenum dichloride |
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