Diastereoselective alkylation of iminomethylenephosphinates possessing an asymmetric center at the phosphorus atom |
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| Authors: | Takehiro Yamagishi |
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| Affiliation: | School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan |
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| Abstract: | Diastereoselective synthesis of α-aminophosphinates was achieved by alkylation of imines with a 1,1-diethoxyethylphosphinyl group. These products were readily converted into α-amino-H-phosphinates. |
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| Keywords: | α-Amino-H-phosphinates Phosphorus Alkylations Diastereoselectivity |
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