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Reactions of 1,4-bis(tetrazole)benzenes: formation of long chain alkyl halides |
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| Authors: | Andrew D Bond Fintan Kelleher Vipa Prajapati |
| Institution: | a Department of Chemistry, University of Southern Denmark, DK-5230 Odense M, Denmark b Department of Science and Advanced Smart Materials Research Center, Institute of Technology, Tallaght, Dublin 24, Ireland c Department of Chemistry, National University of Ireland Maynooth, Maynooth, Co. Kildare, Ireland |
| Abstract: | The reactions of 1,4-bis2-(tributylstannyl)tetrazol-5-yl]benzene with α,ω-dibromoalkanes were carried out in order to synthesise pendant alkyl halide derivatives of the parent bis-tetrazole. This led to the formation of several alkyl halide derivatives, substituted variously at N1 or N2 on the tetrazole ring. The crystal structures of 1,4-bis(2-(4-bromobutyl)tetrazol-5-yl)]benzene (2-N,2-N′), 1,4-bis(2-(4-bromobutyl)tetrazol-5-yl)]benzene (1-N,2-N′) and 1,4-bis(2-(8-bromooctyl)tetrazol-5-yl)]benzene (2-N,2-N′) are reported. Further discussion involves the structure of 1,4-bis2-(6-bromohexyl)-2H-tetrazol-5-yl]benzene (2-N,2-N′) previously reported. |
| Keywords: | Tetrazole Organotin X-ray Alkyl halide NMR spectroscopy |
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