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Dark singlet oxygenation of organic substrates in single-phase and multiphase microemulsion systems |
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| Authors: | Jean-Marie Aubry Waldemar Adam Paul L Alsters Sébastien Queste Véronique Nardello |
| Institution: | a LCOM, Equipe ‘Oxydation & Formulation’, UMR CNRS 8009, École Nationale Supérieure de Chimie de Lille, BP 90108, F-59652 Villeneuve d'Ascq Cedex, France b Department of Chemistry, University of Puerto Rico, Facundo Bueso, 110, Rio Piedras, PR 00931, USA c University of Wuerzburg, Institute of Organic Chemistry, Am Hubland, D-97074 Wuerzburg, Germany d DSM Pharma Chemicals, Advanced Synthesis, Catalysis and Development, PO Box 18, 6160 MD Geleen, The Netherlands |
| Abstract: | The disproportionation of hydrogen peroxide catalyzed by molybdate anions provides an effective non-photochemical source of singlet oxygen 1O2, (1Δg). Microemulsions are the preferred media to carry out ‘dark’ singlet oxygenation of labile and hydrophobic substrates. Single-phase and multiphase microemulsion systems have been developed and improved for the last decade and their respective advantages and limitations are shortly reviewed and discussed. |
| Keywords: | Microemulsion Singlet oxygen Multiphase media Hydrogen peroxide |
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