The synthesis of single enantiomers of meromycolic acids from mycobacterial wax esters |
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Authors: | Juma'a R. Al Dulayymi Evan Roberts |
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Affiliation: | a Department of Chemistry, University of Wales, Bangor, Gwynedd LL 57 2 UW, UK b School of Molecular Sciences, University of Birmingham, Birmingham UK |
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Abstract: | Three stereoisomers of a wax ester meromycolate have been prepared starting from mannitol. A detailed comparison of their NMR spectra with those reported for a homologous series of natural wax esters allows the relative configurations of the α-methyl group and adjacent trans-cyclopropane to be determined. |
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