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Enantiodivergent synthesis of both antipodes of hydroxy-exo-brevicomin from l-(+)-tartaric acid |
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| Authors: | Kavirayani R. Prasad Pazhamalai Anbarasan |
| Affiliation: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India |
| Abstract: | An enantiodivergent approach to both antipodes of hydroxy-exo-brevicomin was achieved from a common chiral precursor l-(+)-tartaric acid. The strategy utilizes the elaboration of a keto-Weinreb amide and successive stereoselective reductions. |
| Keywords: | Stereoselective reduction smallcaps" >l-(+)-Tartaric acid Hydroxy-exo-brevicomin 6,8-Dioxabicyclo[3.2.1]octane |
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