|
|||||
|
|
| 多阴离子和铜磷酸盐为基元的杂化材料的合成、结构和性质 | |
| 引用本文： | 赵志凤,周百斌,苏占华,朱春城. 多阴离子和铜磷酸盐为基元的杂化材料的合成、结构和性质[J]. 无机化学学报, 2009, 25(5): 900-905 |
| 作者姓名： | 赵志凤 周百斌 苏占华 朱春城 |
| 作者单位： | 1. 哈尔滨工业大学化工学院,哈尔滨,150001 2. 哈尔滨工业大学化工学院,哈尔滨,150001;哈尔滨师范大学化学化工学院,哈尔滨,150025 3. 哈尔滨师范大学化学化工学院,哈尔滨,150025 |
| 摘 要： | 本文采用水热法合成了一个新的金属有机-无机杂化化合物 [Cu4(phen)4(HPO4)2(H2O)2(OH)2][HPMo12O40]·H2O (1) ( phen=邻菲咯啉)。通过元素分析、红外光谱、热重分析、X-射线单晶衍射对其进行了结构表征。化合物1是由四核铜磷酸盐、Keggin阴离子和晶格水分子组成。四核铜磷酸盐和多阴离子之间通过弱的M…O相互作用形成二维结构(M=Cu, Mo), 该二维结构通过氢键和π-π相互作用形成三维超分子框架，还对化合物1的电化学和电催化性质进行了研究。 |
| 关 键 词： | 水热合成； 晶体结构； 多金属氧酸盐； 电化学 |
Synthesis, Structure and Properties of A Hybrid Material Based on Polyoxoanion and Copper Phosphate |
|
| ZHAO Zhi-Feng,ZHOU Bai-Bin,SU Zhan-Hua and ZHU Chun-Cheng. Synthesis, Structure and Properties of A Hybrid Material Based on Polyoxoanion and Copper Phosphate[J]. Chinese Journal of Inorganic Chemistry, 2009, 25(5): 900-905 | |
| Authors: | ZHAO Zhi-Feng ZHOU Bai-Bin SU Zhan-Hua ZHU Chun-Cheng |
| Affiliation: | School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001,School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001; Institute of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025,School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001; Institute of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025 and Institute of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025 |
| Abstract: | A new metalorganic-inorganic hybrid compound [Cu4(phen)4(HPO4)2(H2O)2(OH)2][HPMo12O40] ·H2O (1) (phen=l,10－phenanthroline), has been hydrothermally synthesized and structurally characterized by elementalanalysis, IR spectrum, thermal analysis and single-crystal X-ray structural analysis. Compound 1 is consisted of a tetranuclear copper phosphate [Cu4(phen)4(HPO4)2(H2O)2(OH)2]2+, Keggin polyoxoanion [HPMo12O40]2- and the lattice water molecule. Compound 1 generates an interesting 2D network between the tetranuclear copper phosphates and polyoxoanions by weak M---O interactions (M=Cu, Mo), which is further connected into a 3D supramolecular The current version does not support copying Cyrillic text to the Clipboard.fabricate a carbon paste electrode (1－CPE) by direct mixing. The electrochemical and electrocatalytic behaviors of the 1－CPE have been studied in detail. CCDC: 666620. |
| Keywords: | hydrothermal synthesis crystal structure polyoxometalates electrochemistry |
| 本文献已被 维普 万方数据 等数据库收录！ | |
| 点击此处可从《无机化学学报》浏览原始摘要信息 | |
| 点击此处可从《无机化学学报》下载全文 | |