Diastereoselective addition of allyltitanocenes to cyclic enones |
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| Authors: | Takeda Takeshi Nishimura Takuya Yoshida Satoshi Saiki Fumiya Tajima Yuki Tsubouchi Akira |
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| Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan. takeda-t@cc.tuat.ac.jp |
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| Abstract: | The reaction of allyltitanocenes with five- to seven-membered cyclic enones proceeded with good to high diastereoselectivity depending on the ring size of enones. The stereochemistry of the major isomers produced by the reaction of cinnamyltitanocene was opposite to that of crotyltitanocene. |
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