Steric effects on uranyl complexation: synthetic, structural, and theoretical studies of carbamoyl pyrazole compounds of the uranyl(VI) ion |
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Authors: | Das Debasish Kannan Shanmugaperumal Maity Dilip K Drew Michael G B |
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Institution: | Fuel Reprocessing Division, Bhabha Atomic Research Centre, Mumbai-400085, India. |
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Abstract: | New bifunctional pyrazole based ligands of the type C(3)HR(2)N(2)CONR'] (where R = H or CH(3); R' = CH(3), C(2)H(5), or (i)C(3)H(7)) were prepared and characterized. The coordination chemistry of these ligands with uranyl nitrate and uranyl bis(dibenzoyl methanate) was studied with infrared (IR), (1)H NMR, electrospray-mass spectrometry (ES-MS), elemental analysis, and single crystal X-ray diffraction methods. The structure of compound UO(2)(NO(3))(2)(C(3)H(3)N(2)CON{C(2)H(5)}(2))] (2) shows that the uranium(VI) ion is surrounded by one nitrogen atom and seven oxygen atoms in a hexagonal bipyramidal geometry with the ligand acting as a bidentate chelating ligand and bonds through both the carbamoyl oxygen and pyrazolyl nitrogen atoms. In the structure of UO(2)(NO(3))(2)(H(2)O)(2)(C(5)H(7)N(2)CON {C(2)H(5)}(2))(2)], (5) the pyrazole ligand acts as a second sphere ligand and hydrogen bonds to the water molecules through carbamoyl oxygen and pyrazolyl nitrogen atoms. The structure of UO(2)(DBM)(2)C(3)H(3)N(2)CON{C(2)H(5)}(2)] (8) (where DBM = C(6)H(5)COCHCOC(6)H(5)) shows that the pyrazole ligand acts as a monodentate ligand and bonds through the carbamoyl oxygen to the uranyl group. The ES-MS spectra of 2 and 8 show that the ligand is similarly bonded to the metal ion in solution. Ab initio quantum chemical studies show that the steric effect plays the key role in complexation behavior. |
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