Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst |
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| Authors: | Gharah Narottam Chakraborty Santu Mukherjee Alok K Bhattacharyya Ramgopal |
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| Affiliation: | Department of Chemistry, Jadavpur University, Kolkata, India. |
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| Abstract: | A combination of the newly synthesized and structurally characterized compound, [MoO(O2)2(saloxH)](saloxH2= salicylaldoxime) as catalyst, H2O2 as terminal oxidant and NaHCO3 as co-catalyst when stirred in CH3CN (10 cm3) at room temperature (rt) shows a very pronounced efficiency epoxidation of olefinic compounds, the method being green and economical. |
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