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High-pressure and -temperature ion exchange of aluminosilicate and gallosilicate natrolite
Authors:Hill Gemma L  Bailey Edward  Stennett Martin C  Hyatt Neil C  Maddrell Ewan M  McMillan Paul F  Hriljac Joseph A
Institution:School of Chemistry, University of Birmingham, Edgbaston, UK.
Abstract:The simultaneous application of high pressure and high temperature has been used to achieve direct ion exchange of large cesium cations for the small sodium cations found in the zeolite natrolite by putting it into a superhydrated state with increased pore size. The larger cations remain trapped upon pressure release, and thus, this method is a means of producing new cationic forms of zeolites.
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