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Nuclear magnetic resonance relaxation of methane protons in aqueous solutions
Authors:T Raj  B Borah  R M Riddle  R G Bryant
Institution:(1) Department of Chemistry, University of Minnesota, 55455 Minneapolis, MN
Abstract:Proton nuclear magnetic resonance longitudinal relaxation rates are reported at 100MHz for CH4 and CHD3 in deuterium oxide solutions. The results demonstrate that methane reorients with a correlation time on the order of 0.1 psec, considerably faster than molecule correlation times in aqueous solutions.
Keywords:NMR relaxation  methane  correlation times  aqueous solutions
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