Feasibility of a low-voltage discharge in pure molecular hydrogen

The feasibility of initiating a low-voltage discharge in pure (free of readily ionizable impurity) molecular hydrogen is studied theoretically. A discharge with cathode fall φ₁ = 10 V, interelectrode gap L = 2 cm, and total hydrogen concentration \(N_{H_2 }^{(0)} = 2 \times 10^{15}\) cm^?3 is considered by way of example. The plasma parameters, including concentration \(N_{H^ - }\) of negative hydrogen ions H^?, are calculated. The concentration of H^? ions is maximal in the near-anode plasma and may reach \(\left( {N_{H^ - } } \right)_{\max } = 0.5 \times 10^{12}\) cm^?3. Concentration \(N_{H^ - }\) can be increased severalfold by introducing a small amount of cesium into the discharge, \(N_{Cs}^{(0)} \leqslant 10^{13}\) cm^?3. Cesium ionizes completely and concentrates in narrow near-electrode layers, which are depleted with the plasma in the purely hydrogen discharge. The discharge modifications studied in this work may be of interest as low-voltage volume plasma sources of H^? ions under conditions when a high concentration of cesium in the source plasma is undesirable.