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MW-assisted Er(OTf)3-catalyzed mild cleavage of isopropylidene acetals in Tricky substrates |
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| Authors: | Antonio Procopio Marco Gaspari Manuela Oliverio |
| Institution: | a Dipartimento Farmaco-Biologico, Università degli Studi della Magna Grascia Complesso Nin?` Barbieri, 88021, Roccelletta di Borgia (CZ), Italy b Dipartimento di Chimica, Università della Calabria, Ponte Bucci, 87030, Arcavacata di Rende (CS), Italy c Dipartimento Farmaco-Chimico Università di Messina, Messina, Italy |
| Abstract: | Erbium(III) trifluoromethane sulfonate is proposed as a very gentle Lewis acid catalyst in a MW-assisted chemoselective method for the cleavage of isopropylidene acetals in awkward substrates by using pure water as the solvent. |
| Keywords: | Isopropylidene acetal Erbium(III) triflate MW-assisted synthesis Water as solvent |
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