(1) Babes-Bolyai University, Organic Chemistry Department and CSOFSTM, RO-3400, Cluj-Napoca, Romania, RO;(2) Université de Rouen, IRCOF, UMR 6014, Faculté des Sciences, 76821 Mont Saint-Aignan, Cedex, France, FR
Abstract:
Summary. The synthesis and stereochemistry of some new 2,5-substituted 1,3-oxathiane derivatives are reported. The anancomeric or flexible structure of the derivatives and some peculiar cases of prochirality are revealed by NMR investigations.