3D homometallic carboxylate ferrimagnet constructed from a manganese(II) succinate carboxylate layer motif pillared by isonicotinate spacers |
| |
| Authors: | Zeng Ming-Hua Wu Mei-Chun Liang Hong Zhou Yan-Ling Chen Xiao-Ming Ng Seik-Weng |
| |
| Affiliation: | Department of Chemistry and Chemical Engineering, GuangXi Normal University, Guilin 541004, People's Republic of China. zmh@mailbox.gxnu.edu.cn |
| |
| Abstract: | A manganese succinate having a layer structure in which the layers are pillared by the isonicotinate spacers in a 3D architecture exhibits long-range ferrimagnetic order below 5.0 K, with the ferrimagnetism arising, for topological reasons, from the nature of the carboxylate binding modes. The compound is the first structurally authenticated example of a 3D ferrimagnet, featuring a homometallic topological ferrimagnetic sheet among metal carboxylates. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
