TcCl4(H2O)2] and [Cl3(H2O)2TcOTc(H2O)2Cl3]--two molecular intermediates of the hydrolysis of technetium(IV) |
| |
| Authors: | Yegen Eda Hagenbach Adelheid Abram Ulrich |
| |
| Affiliation: | Freie Universit?t Berlin, Institut für Chemie und Biochemie, Fabeckstr. 34-36, 14195, Berlin, Germany. |
| |
| Abstract: | Two molecular intermediates of the hydrolysis of technetium tetrachloride, cis-[TcCl4(H2O)2] and [Cl3(H2O)2TcOTc(H2O)2Cl3], were isolated and structurally characterised, suggesting that the hydrolytic degradation of technetium(IV) compounds occurs stepwise with the polymeric 'TcO2...nH2O' as a less defined final product. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
