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Crystal and molecular structure of trans-bis(dodecylamine) bis(dimethylglyoximato)cobalt(III) nitrite
Authors:P Laavanya  K Panchanatheswaran  M N Arumugam  S Arunachalam
Institution:(1) Department of Chemistry, Bharathidasan University, Tiruchirappalli- 620 024, Tamil Nadu, India
Abstract:An octahedral geometry for the molecule of the title complex with very slight distortions around Co(III) is confirmed by single-crystal X-ray diffraction study. The molecular structure of the complex has been shown to contain two dodecylamine moieties in the trans orientations, two N-bonded dimethylglyoximato (DMG) groups and an uncoordinated nitrite ion.
Keywords:X-ray crystal structure  cobalt(III) complexes  dodecylamine
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