Ethanol and water adsorption in methanol-derived ZIF-71 |
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| Authors: | Lively Ryan P Dose Michelle E Thompson Joshua A McCool Benjamin A Chance Ronald R Koros William J |
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| Affiliation: | Algenol Biofuels, 28100 Bonita Grande Drive, Bonita Springs, FL 34315, USA. ryan.lively@algenol.com |
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| Abstract: | A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. |
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