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Stereoselective total synthesis of alkaloid caulophyllumine B using iterative olefin cross-metathesis protocol |
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| Authors: | Palakodety Radha Krishna Bonepally Karunakar Reddy |
| Institution: | D-211, Discovery Laboratory, Organic Chemistry Division-III, Indian Institute of Chemical Technology, Hyderabad 500 607, India |
| Abstract: | Herein we report the first total synthesis of alkaloid caulophyllumine B in 14 steps by an iterative olefin cross-metathesis strategy from l-glutamic acid. |
| Keywords: | Piperidine alkaloids Cytochrome P450 Grubbs-II catalyst Iterative olefin cross-metathesis |
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