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Stereoselective synthesis of aminocyclitol moieties of trehazolin and trehalostatin via enyne metathesis protocol |
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| Authors: | Palakodety Radha Krishna Munagala Alivelu |
| Institution: | D-211, Discovery Laboratory, Organic Chemistry Division-III, Indian Institute of Chemical Technology, Hyderabad 500 607, India |
| Abstract: | Stereoselective and efficient synthesis of respective aminocyclitol moieties 1a and 2a of trehazolin and trehalostatin as hexaacetates 1b and 2b using ring-closing enyne metathesis as the key reaction is described. |
| Keywords: | Aminocyclitols Wittig olefination Enyne metathesis Regioselective dihydroxylation Sharpless asymmetric epoxidation Substrate directed dihydroxylation |
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