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Organocatalyzed synthesis of ureas from amines and ethylene carbonate
Authors:Francesco Saliu  Bruno Rindone
Institution:Department of Environmental Science, University of Milano-Bicocca, Piazza della Scienza 1, 20126 Milano, Italy
Abstract:A new solventless method for the synthesis of symmetrical and unsymmetrical ureas, starting from ethylene carbonate and amines, is reported. 1,5,7-Triazabicyclo4.4.0]dec-5-ene(TBD) and thioureas have been found to be efficient organocatalysts for this reaction.
Keywords:2-Hydroxyethylcarbamates  1  3-Disubstituted ureas  Organic catalysis  Solventless reaction
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