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Synthesis and properties of TTFV-hinged molecular tweezers
Authors:Guang Chen
Affiliation:Department of Chemistry, Meorial University of Newfoundland, St. John’s, NL, Canada A1B 3X7
Abstract:Two molecular tweezers containing a tetrathiafulvalene vinylogue (TTFV) core were synthesized via sequential Sonogashira and Horner-Wadsworth-Emmons (HWE) reactions. The electrochemical and spectroscopic properties of these TTFV tweezers were investigated by UV-vis absorption spectroscopy, cyclic voltammetry, and spectro-electrochemical measurements. The property characterizations suggest potential application in electrochemically-actuated molecular switching devices.
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