Molecular iodine-promoted N- and C-glycosylation of 1-C-alkyl (or phenyl)-glycopyranoses |
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| Authors: | A.P. John Pal |
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| Affiliation: | Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India |
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| Abstract: | Molecular iodine efficiently promoted the N- and C-glycosylation of hemiketals with Me3SiN3 and Me3SiCN, respectively. Using this method we have prepared diverse functional N- and C-ketosides, which could serve as useful synthons for the preparation of unnatural glycosyl amino acids or glycopeptides. |
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| Keywords: | Molecular iodine Ketoses Glycosylation N-Ketosides C-Ketosides |
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