TMSCl-promoted selective oxidation of sulfides to sulfoxides with hydrogen peroxide |
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| Authors: | Kiumars Bahrami Mohammad M. Khodaei Behrooz H. Yousefi |
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| Affiliation: | a Department of Chemistry, Razi University, Kermanshah 67149-67346, Iran
b Department of Nuclear Medicine, Klinikum rechts der Isar, Technische Universität München, Ismaninger Straße 22, D-81675 Munich, Germany |
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| Abstract: | Selective oxidation of sulfides to sulfoxides is achieved using H2O2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated. |
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