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Novel receptors with quinoline and amide moieties for the biologically important ions
Authors:Jongmin Kang  Seung Pyo Jang  Ju Hoon Lee  Hong Gyu Lee  Youngmee Kim  Cheal Kim
Institution:a Department of Chemistry, Institute for Chemical Biology, Sejong University, Seoul 143-747, Republic of Korea
b Department of Fine Chemistry, and Eco-Product and Materials Education Center, Seoul National University of Technology, Seoul 139-743, Republic of Korea
c Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Republic of Korea
Abstract:New chromogenic anion receptors 2 and 4 utilizing quinoline and nitrophenyl groups as signaling groups were synthesized. In these receptors, amide and amine groups made strong multiple hydrogen interactions with anions. The receptors 2 and 4 bind anions with a selectivity of F > CN > View the MathML source and proved to be an efficient naked-eye detector for the fluoride and cyanide ion.
Keywords:Anion receptor  Colorimetric receptor  Hydrogen bond
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