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Aerobic oxidative dehydrogenation of benzylamines catalyzed by a cyclometalated ruthenium complex
Authors:Ayako Taketoshi  Takaki Kanbara
Affiliation:a Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba 305-8573, Japan
b Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
Abstract:The ruthenium(III) complex bearing phenylpyridine as a cyclometalated ligand serves as an efficient catalyst for the aerobic oxidative dehydrogenation of benzylamines to the corresponding benzonitriles under mild conditions.
Keywords:Dehydrogenation   Homogeneous catalysis   Ruthenium   Amine
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