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Synthesis and electrochemical behavior of a model redox-active thiacalix[4]arene-tetrathiafulvalene assembly |
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| Authors: | Bang-Tun Zhao Zhen Zhou Esmah Belhadj Franck Le Derf |
| Institution: | a Department of Chemistry, Luoyang Normal University, Luoyang 471022, PR China b Department of Chemistry, Zhengzhou University, Zhengzhou 450001, PR China c Laboratoire MOLTECH-Anjou, UMR-CNRS 6200,Université d’Angers, 2 Bd Lavoisier, Angers, France d Laboratoire de Synthèse Organique Appliquée, Université d’Oran Es-Senia, BP 1524 El M’Naouer, Oran, Algeria |
| Abstract: | Syntheses of the first bisthiacalix4]arenes systems bridged by a tetrathiafulvalene (TTF) framework have been carried out through triethyl phosphite-mediated dechalcogenation dimerization of the corresponding 1,3-dithiole-2-ones. The cyclic voltammograms of the resulting bisthiacalix4]arenes tethered by an electroactive TTF unit are provided, and exhibit an electrochemical response in the case of introduction of Ag+. |
| Keywords: | Thiacalix[4]arene Tetrathiafulvalene Cyclic voltammetry |
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